Advances in Molten Salt Chemistry: Volume 1 - download pdf or read online

By Ronald E. Hester (auth.), J. Braunstein, Gleb Mamantov, G. P. Smith (eds.)

ISBN-10: 1475705042

ISBN-13: 9781475705041

ISBN-10: 1475705069

ISBN-13: 9781475705065

Molten salts are investigated through very assorted thoughts and for fluctuate­ ing reasons, and the implications are suggested in commonly scattered journals. there's a have to retain investigators conscious of development in different specialties and to supply scholars with resource and historical past fabric. Advances in Molten Salt Chemistry hopes to fill those wishes via supplying studies of contemporary development offered, insofar as is affordable, with sufficient heritage fabric and observation to be understandable to a nonspecialist. We favor a dialogue of underlying ideas, to the level that they're recognized, and we motivate authors to remark seriously at the reliability of information, the software of types, and the cogency of principles and theories. We take a large vie~ of the suitability of subject matters for inclusion during this sequence. either primary and technological advances have a spot the following, as do reports on fabrics regarding molten salts (like liquid silicates, very targeted aqueous options, strategies of salts in liquid metals, and strong electrolytes). We intend this sequence to serve the wishes of these who examine or use molten salts. We welcome feedback of subject matters and appropriate authors, in addition to reviews at the strengths and shortcomings of what's published.

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Extra resources for Advances in Molten Salt Chemistry: Volume 1

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Molten AlCI a . NaCI gave four Raman bands, as listed in Table II, the 349 cm-I band being polarized and more than three times more intense than any other. (69 ,70) A tetrahedral AICI 4- ion offers a ready explanation of this spectrum. However, when KCI was used in place of NaCI in the AICla/MCI mixtures, a more complex nine-band spectrum was observed. (69) This was interpreted as arising from a removal of degeneracy from some of the AICl 4- ion modes, caused by strong cationic distortion to C 2V symmetry, but the spectra were of rather poor quality and might be reinterpreted differently.

42 to 00) at 900C. 1116) with the later species becoming progressively more important with decreasing water content. " Figure 25, however, offers still more conclusive spectroscopic evidence for the displacement of innersphere water molecules by nitrate ions in the molten hexahydrate of zinc nitrate. The symmetrical singlet structure of the viE') band of N0 3- in the solid, where it is known to be separated from the nearest Zn2+ by a layer of water molecules, (11S) splits into a widely spaced doublet in the melt, consistent with the proposed ligand-exchange process occurring in the liquid.

HgCl. HgCII HgBrI Cdt" (48)R, (60)R (60)R (54)R, Ronald E. Hester 30 TABLE II. /KCI AICI4-(Td ) AICI4-(C. AIF6 GaCl s GaBr. InCl. -n complexes and lattice 240,480,520,720 (29)1 Group IVA SnCI. /KCl Group IVB ZrF4/KF/MF (M = Li, K) a I = reference concerned with infrared spectra and R = reference concerned with Raman spectra. spectra(55) either. Since there is bound to be some uncertainty in assignments, those given in Table II are uniformly taken from the original publications. While generally rejecting the existence of complex ions in fused salts, Wilmshurst(28) interpreted his infrared spectra from the CuCi 2/KCI system as being at least fully consistent with the existence of the CuCI~- species in these melts.

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Advances in Molten Salt Chemistry: Volume 1 by Ronald E. Hester (auth.), J. Braunstein, Gleb Mamantov, G. P. Smith (eds.)

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