Read e-book online Aquatic Redox Chemistry PDF

By Paul G. Tratnyek, Timothy J. Grundl, and Stefan B. Haderlein (Eds.)

ISBN-10: 0841226520

ISBN-13: 9780841226524

ISBN-10: 0841226539

ISBN-13: 9780841226531

content material: PREFACE ; 1. creation TO AQUATIC REDOX CHEMISTRY ; TIMOTHY J. GRUNDL, STEFAN HADERLEIN, JAMES T. NURMI, AND PAUL G. TRATNYEK ; 2. THERMODYNAMIC REDOX CALCULATIONS FOR ONE AND ELECTRON move STEPS: IMPLICATIONS FOR HALIDE OXIDATION AND HALOGEN ENVIRONMENTAL biking ; GEORGE W. LUTHER, III ; three. ONE-ELECTRON aid POTENTIALS FROM CHEMICAL constitution concept CALCULATIONS ; ERIC J. BYLASKA, ALEXANDRA J. SALTER-BLANC, AND PAUL G. TRATNYEK ; four. THERMODYNAMIC regulate ON TERMINAL ELECTRON move AND METHANOGENESIS ; CHRISTIAN BLODAU ; five. REDOX CHEMISTRY AND ordinary natural topic (NOM): GEOCHEMISTS' DREAM, ANALYTICAL CHEMISTS>' NIGHTMARE ; DONALD L. MACALADY AND KATHERINE WALTON-DAY ; 6. ELECTRON SHUTTLING via average natural topic: 20 years AFTER ; GARRISON SPOSITO ; 7. ELECTROCHEMISTRY OF ordinary natural subject ; JAMES T. NURMI AND PAUL G. TRATNYEK ; eight. PATHWAYS CONTRIBUTING TO THE FORMATION and rot OF FERROUS IRON IN SUNLIT normal WATERS ; SHIKHA GARG, ANDREW L. ROSE, AND T. DAVID WAITE ; nine. THE function OF IRON COORDINATION within the construction OF REACTIVE OXIDANTS FROM FERROUS IRON OXIDATION through OXYGEN AND HYDROGEN PEROXIDE ; CHRISTINA KEENAN REMUCAL AND DAVID L. SEDLAK ; 10. TIO2 PHOTOCATALYSIS FOR THE REDOX CONVERSION OF AQUATIC toxins ; JAESANG LEE, JUNGWON KIM, AND WONYONG CHOI ; eleven. CHLORINE established OXIDANTS FOR WATER PURIFICATION AND DISINFECTION ; GREGORY V. KORSHIN ; 12. REMEDIATION OF CHEMICALLY-CONTAMINATED WATERS utilizing SULFATE RADICAL REACTIONS: KINETIC reviews ; STEPHEN P. MEZYK, KIMBERLY A. RICKMAN, GARRETT MCKAY, CHARLOTTE M. HIRSCH, XUEXIANG HE, AND DIONYSIOS D. DIONYSIOU ; thirteen. VOLTAMMETRY OF SULFIDE NANOPARTICLES AND THE FES(AQ) challenge ; G. R. HELZ, I. CIGLENECKI, D. KRZNARIC, AND E. BURA-NAKIC ; 14. REDOX REACTIVITY OF ORGANICALLY COMPLEXED IRON(II) SPECIES WITH AQUATIC CONTAMINANTS TIMOTHY J. STRATHMANN ; 15. FE2+ SORPTION on the FE OXIDE-WATER INTERFACE: A REVISED CONCEPTUAL FRAMEWORK ; CHRISTOPHER A. GORSKI AND MICHELLE M. SCHERER ; sixteen. REDOX pushed sturdy ISOTOPE FRACTIONATION ; JAY R. BLACK, JEFFREY A. CRAWFORD, SETH JOHN, AND ABBY KAVNER ; 17. REDOX houses OF STRUCTURAL FE IN SMECTITE CLAY MINERALS ; ANKE NEUMANN, MICHAEL SANDER, AND THOMAS B. HOFSTETTER ; 18. REACTIVITY OF ZEROVALENT METALS IN AQUATIC MEDIA: results OF natural floor COATINGS ; PAUL G. TRATNYEK, ALEXANDRA J. SALTER-BLANC, JAMES T. NURMI, JAMES E. AMONETTE, JUAN LIU, CHONGMIN WANG, ALICE DOHNALKOVA, AND DONALD R. BAER ; 19. present views at the MECHANISMS OF CHLOROHYDROCARBON DEGRADATION IN SUBSURFACE ENVIRONMENTS: perception FROM KINETICS, PRODUCT FORMATION, PROBE MOLECULES, AND ISOTOPE FRACTIONATION ; MARTIN ELSNER AND THOMAS B. HOFSTETTER ; 20. DEGRADATION ROUTES OF RDX IN a variety of REDOX platforms ; ANNAMARIA HALASZ AND JALAL HAWARI ; 21. function OF COUPLED REDOX ameliorations within the MOBILIZATION AND SEQUESTRATION OF ARSENIC ; JANET G. HERING, STEPHAN J. HUG, CLAIRE FARNSWORTH, AND PEGGY A. O>'DAY ; 22. REDOX methods AFFECTING THE SPECIATION OF TECHNETIUM, URANIUM, NEPTUNIUM, AND PLUTONIUM IN AQUATIC AND TERRESTRIAL ENVIRONMENTS ; EDWARD J. O'LOUGHLIN, MAXIM I. BOYANOV, DIONYSIOS A. ANTONOPOULOS, AND KENNETH M. KEMNER ; 23. fee CONTROLLING techniques within the TRANSFORMATION OF TETRACHLOROETHYLENE AND CARBON TETRACHLORIDE lower than IRON lowering AND SULFATE lowering stipulations ; ELIZABETH C. BUTLER, YIRAN DONG, LEE R. KRUMHOLZ, XIAOMING LIANG, HONGBO SHAO, AND YAO TAN ; 24. using CHEMICAL PROBES FOR THE CHARACTERIZATION OF THE major ABIOTIC REDUCTANTS IN ANAEROBIC SEDIMENTS ; HUICHUN (JUDY) ZHANG, DALIZZA COLON, JOHN F. KENNEKE, AND ERIC J. WEBER ; 25. THE function OF delivery IN AQUATIC REDOX CHEMISTRY ; WOLFGANG KURTZ AND STEFAN PEIFFER ; 26. EVOLUTION OF REDOX tactics IN GROUNDWATER ; PETER B. MCMAHON, FRANCIS H. CHAPELLE, AND PAUL M. BRADLEY ; EDITORS' BIOGRAPHIES ; INDEXES ; writer INDEX ; topic INDEX

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Ch002 M. ; Saltzman, E. ; Heard, D. E. The chemistry of OH and HO2 radicals in the boundary layer over the tropical Atlantic Ocean. Atmos. Chem. Phys. 2010, 10, 1555–1576. 35. Huheey, J. ; Keiter, E. ; Keiter, R. L. ; Harper Collins; New York, NY, 1993; p A-30. ; ACS Symposium Series; American Chemical Society: Washington, DC, 2011. ch003 One-Electron Reduction Potentials from Chemical Structure Theory Calculations Eric J. Bylaska,1 Alexandra J. Salter-Blanc,2 and Paul G. O. edu Many redox reactions of importance in aquatic chemistry involve elementary steps that occur by single-electron transfer (SET).

Tratnyek, P. One-electron reduction potentials from chemical structure theory calculations. , Grundl, T. , Haderlein, S. ; American Chemical Society: Washington, DC, 2011; Vol. 1071, Chapter 3, pp 37−64. , Morgan J. J. ; John Wiley: New York, 1996; p 1022. Bard, A. ; M. Dekker: New York, 1985, p 834. Stanbury, D. Reduction potentials involving inorganic free radicals in aqueous solution. In Advances in Inorganic Chemistry; Sykes, A. ; Academic Press: New York, 1989; Vol. 33, pp 69−138. ; Luther, G.

This approach self-consistently minimizes the electrostatic energy by optimizing the polarization of the continuous medium and charge distribution of the solute. The cavitation and dispersion contributions to the solvation energy are less straightforward to handle because the interactions take place at short distances. There are several proposed ways to do this (42, 44, 49–54). ; ACS Symposium Series; American Chemical Society: Washington, DC, 2011. expressions that depend only on the solvent accessible surface area.

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Aquatic Redox Chemistry by Paul G. Tratnyek, Timothy J. Grundl, and Stefan B. Haderlein (Eds.)


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