C-X Bond Formation - download pdf or read online

By Kilian Muñiz (auth.), Arkadi Vigalok (eds.)

ISBN-10: 3642120725

ISBN-13: 9783642120725

Kilian Muñiz: Transition steel Catalyzed Electrophilic Halogenation of C-H bonds in alpha-Position to Carbonyl teams; Arkadi Vigalok and Ariela W Kaspi: overdue Transition Metal-Mediated Formation of Carbon-Halogen Bonds; Paul Bichler and Jennifer A. Love: Organometallic methods to Carbon-Sulfur Bond Formation; David S. Glueck: fresh Advances in Metal-Catalyzed C-P Bond Formation; Andrei N. Vedernikov: C-O Reductive removal from excessive Valent Pt and Pd facilities; Lukas Hintermann: fresh advancements in Metal-Catalyzed Additions of Oxygen Nucleophiles to Alkenes and Alkynes; Moris S. Eisen: Catalytic C-N, C-O and C-S bond formation promoted via organoactinide complexes.

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3 Reactions with Alkenes . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 57 4 Summary and Conclusion . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 59 References . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 59 P. A. ca 40 P. A. Love Abbreviations % Acac AcOH atm BINAM ÆBINAP [bmim][OTf] Bn Bu C–S CH3CN cod Conv.

59 P. A. ca 40 P. A. Love Abbreviations % Acac AcOH atm BINAM ÆBINAP [bmim][OTf] Bn Bu C–S CH3CN cod Conv. , Vioxx and Celebrex), the asthma drug Singulair and the antibiotic griseoviridin [1–5]. A wide variety of synthetic methods are needed to construct these molecules, given their apparent structural diversity. As such, the formation and further functionalization of C–S bonds have received considerable attention. Sulfides, thiols, and their oxidized derivatives are also widely utilized in a number of synthetic transformations, ranging from Diels–Alder cycloadditions [6, 7] to sigmatropic rearrangements [8], act as acyl anion equivalents [9] and are used in the synthesis of olefins [10].

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C-X Bond Formation by Kilian Muñiz (auth.), Arkadi Vigalok (eds.)


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